There are some pretty messed up petitions being entertained there. I do, however think this one is appropriate.
Force all states to pay their portion of the national debt before they can secede from the union
Residents of all states who wish to secede from the union should be required to take their own advice about 'personal responsibility', and pay their share of the national debt before being released to fend for themselves.
This debt must be paid in full, or they cannot leave.
This means no federal assistance, period.
Abridged list includes no more upkeep for highways, nor for interstates or bridges, no federally funded law enforcement or fire department, no public libraries, no phone lines, no cable television, no cell phone towers, no power grids, no water lines, no mail services, no paramedics, no hospitals which accept Medicare/Medicaid funding, no ATF, FBI, DOJ, SWAT, or Department of Homeland Security, no Border Guard, National Guard, Coast Guard, Corps of Engineers, or WITSEC.